∵在正方形ABCD中,E是BC的中点,F是CD上一点,且CF= 1 4 CD,∴∠B=∠C=90°,AB:EC=BE:CF=2:1.∴△ABE∽△ECF.∴AB:EC=AE:EF,∠AEB=∠EFC.∵BE=CE,∠FEC+∠EFC=90°,∴AB:AE=BE:EF,∠AEB+∠FEC=90°.∴∠AEF=∠B=90°.∴△ABE∽△AEF,AE⊥EF.∴②③正确.故答案为②③.