根据题意可得: x※(4※1)=7, x※(4×3-1×2)=7, x※10=7, 3x-10×2=7, 3x-20=7, 3x-20+20=7+20, 3x=27, 3x÷3=27÷3, x=9; x※4, =9※4, =9×3-4×2, =27-8, =19.故选:C.