31g Na2O的物质的量= 31g 62g/mol =0.5mol,溶于水生成NaOH,根据Na元素守恒n(NaOH)=2×0.5mol=1mol,故所得NaOH溶液的物质的量浓度= 1mol 0.5L =2mol/L,故选A.